Whilst I personally couldn't pull off her outfit, the striking thing about it is its individuality. That and the little details that aren't immediately noticeable...the earrings, the shoes...the more I look at this picture, the more things I notice.
I know its been done before, but hi-tops + well fitted jeans + top button done up + large nerdy glasses (forgot to ask where from...I'm new to this) equals winner. Always.